{"id":1497,"date":"2024-05-24T15:56:06","date_gmt":"2024-05-24T07:56:06","guid":{"rendered":"https:\/\/www.k-15.cn\/index.php\/archives\/1497"},"modified":"2024-05-24T15:56:06","modified_gmt":"2024-05-24T07:56:06","slug":"34-%e4%ba%8c%e6%b0%af%e8%8b%af%e8%83%ba","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/index.php\/archives\/1497","title":{"rendered":"3,4-\u4e8c\u6c2f\u80fa"},"content":{"rendered":"<p>    \t\t\t\t\t\t<img decoding=\"async\" src=\"http:\/\/staticv5.basechem.org\/img\/tupu\/old\/392631f3f2f94dd787e8703771e7fbef.gif\" alt=\"3,4-\u4e8c\u6c2f\u80fa\u7ed3\u6784\u5f0f\"><\/p>\n<p>\u7ed3\u6784\u5f0f<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">\u7269\u7ade\u7f16\u53f7<\/th>\n<td>029S<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u5f0f<\/th>\n<td>C6H5Cl2N<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u91cf<\/th>\n<td>162<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u6807\u7b7e<\/th>\n<td>\n<p>                        \u82b3\u9999\u65cf\u542b\u6c2e\u5316\u5408\u7269\u53ca\u5176\u884d\u751f\u7269<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">\u7f16\u53f7\u7cfb\u7edf<\/a><\/li>\n<li><a href=\"#wx\">\u7269\u6027\u6570\u636e<\/a><\/li>\n<li><a href=\"#dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#st\">\u751f\u6001\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/a><\/li>\n<li><a href=\"#js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                    <a href=\"\" class=\"dropdown-toggle\" data-toggle=\"dropdown\">\u66f4\u591a <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/a><\/li>\n<li><a href=\"#zc\">\u8d2e\u5b58\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#hc\">\u5408\u6210\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#yt\">\u7528\u9014<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">\u7f16\u53f7\u7cfb\u7edf<\/h2>\n<p><b>CAS\u53f7\uff1a<\/b>95-76-1<\/p>\n<p><b>MDL\u53f7\uff1a<\/b>MFCD00007768<\/p>\n<p><b>EINECS\u53f7\uff1a<\/b>202-448-4<\/p>\n<p><b>RTECS\u53f7\uff1a<\/b>BX2625000<\/p>\n<p><b>BRN\u53f7\uff1a<\/b>636837<\/p>\n<p><b>PubChem\u53f7\uff1a<\/b>24867396<\/p>\n<h2 id=\"wx\">\u7269\u6027\u6570\u636e<\/h2>\n<p><p>1.\u6027\u72b6\uff1a\u8910\u8272\u9488\u72b6\u7ed3\u6676\u3002<sup>[1]<\/sup><\/p>\n<p>2.\u7194\u70b9\uff08\u2103\uff09\uff1a70~72.5<sup>[2]<\/sup><\/p>\n<p>3.\u6cb8\u70b9\uff08\u2103\uff09\uff1a272<sup>[3]<\/sup><\/p>\n<p>4.\u76f8\u5bf9\u5bc6\u5ea6\uff08\u6c34=1\uff09\uff1a1.33<sup>[4]<\/sup><\/p>\n<p>5.\u76f8\u5bf9\u84b8\u6c14\u5bc6\u5ea6\uff08\u7a7a\u6c14=1\uff09\uff1a5.59<sup>[5]<\/sup><\/p>\n<p>6.\u9971\u548c\u84b8\u6c14\u538b\uff08kPa\uff09\uff1a0.13\uff0880.5\u2103\uff09<sup>[6]<\/sup><\/p>\n<p>7.\u4e34\u754c\u538b\u529b\uff08MPa\uff09\uff1a4.1<sup>[7]<\/sup><\/p>\n<p>8.\u8f9b\u9187\/\u6c34\u5206\u914d\u7cfb\u6570\uff1a2.69<sup>[8]<\/sup><\/p>\n<p>9.\u95ea\u70b9\uff08\u2103\uff09\uff1a166\uff08OC\uff09<sup>[9]<\/sup><\/p>\n<p>10.\u5f15\u71c3\u6e29\u5ea6\uff08\u2103\uff09\uff1a265<sup>[10]<\/sup><\/p>\n<p>11.\u7206\u70b8\u4e0a\u9650\uff08%\uff09\uff1a7.2\uff08179\u2103\uff09<sup>[11]<\/sup><\/p>\n<p>12.\u7206\u70b8\u4e0b\u9650\uff08%\uff09\uff1a2.8\uff08153\u2103\uff09<sup>[12]<\/sup><\/p>\n<p>13.\u6eb6\u89e3\u6027\uff1a\u5fae\u6eb6\u4e8e\u6c34\uff0c\u6eb6\u4e8e\u591a\u6570\u6709\u673a\u6eb6\u5242\u3002<sup>[13]<\/sup><\/p>\n<\/p>\n<h2 id=\"dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/h2>\n<p><p><strong>1.\u6025\u6027\u6bd2\u6027<sup>[14]<\/sup><\/strong> LD50\uff1a545mg\/kg\uff08\u5927\u9f20\u7ecf\u53e3\uff09<\/p>\n<p><strong>2.\u523a\u6fc0\u6027<sup>[15]<\/sup><\/strong><\/p>\n<p>\u5bb6\u5154\u7ecf\u76ae\uff1a2mg\uff0824h\uff09\uff0c\u91cd\u5ea6\u523a\u6fc0\u3002<\/p>\n<p>\u5bb6\u5154\u7ecf\u773c\uff1a250\u03bcg\uff0824h\uff09\uff0c\u91cd\u5ea6\u523a\u6fc0\u3002<\/p>\n<p><strong>3.\u81f4\u7a81\u53d8\u6027<sup>[16]<\/sup><\/strong>&nbsp; \u5fae\u751f\u7269\u81f4\u7a81\u53d8\uff1a\u6784\u5de2\u66f2\u9709200mg\/L\u3002\u59d0\u59b9\u67d3\u8272\u5355\u4f53\u4ea4\u6362\uff1a\u4eba\u6dcb\u5df4\u7ec6\u80de125\u03bcmol\/L\u3002<\/p>\n<\/p>\n<h2 id=\"st\">\u751f\u6001\u5b66\u6570\u636e<\/h2>\n<p><p><strong>1.\u751f\u6001\u6bd2\u6027<sup>[17]<\/sup><\/strong><\/p>\n<p>LC50\uff1a7.26~8.95mg\/L\uff0896h\uff09\uff08\u9ed1\u5934\u5446\u9c7c\uff0c36d\uff09\uff1b\uff1c0.1mg\/L\uff0896h\uff09\uff08\u6c34\u86a4\uff09<\/p>\n<p><strong>2.\u751f\u7269\u964d\u89e3\u6027<\/strong>&nbsp; \u6682\u65e0\u8d44\u6599<\/p>\n<p><strong>3.\u975e\u751f\u7269\u964d\u89e3\u6027<sup>[18] <\/sup><\/strong>&nbsp;\u7a7a\u6c14\u4e2d\uff0c\u5f53\u7f9f\u57fa\u81ea\u7531\u57fa\u6d53\u5ea6\u4e3a5.00\u00d710<sup>5<\/sup>\u4e2a\/cm<sup>3<\/sup>\u65f6\uff0c\u964d\u89e3\u534a\u8870\u671f\u4e3a17h\uff08\u7406\u8bba\uff09\u3002<\/p>\n<p><strong>4.\u751f\u7269\u5bcc\u96c6\u6027<sup>[19]<\/sup><\/strong>&nbsp; BCF\uff1a30.2\uff08\u6591\u9a6c\u9c7c\uff0c\u63a5\u89e6\u65f6\u95f410h\uff09<\/p>\n<\/p>\n<h2 id=\"fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/h2>\n<p><p>1\u3001\u6469\u5c14\u6298\u5c04\u7387\uff1a40.27<\/p>\n<p>2\u3001\u6469\u5c14\u4f53\u79ef\uff08cm<sup>3<\/sup>\/mol\uff09\uff1a115.6<\/p>\n<p>3\u3001\u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a304.8<\/p>\n<p>4\u3001\u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a48.3<\/p>\n<p>5\u3001\u6781\u5316\u7387\uff0810-24cm3\uff09\uff1a15.96<\/p>\n<\/p>\n<h2 id=\"js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/h2>\n<p><p>1.\u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09:\u65e0<\/P><\/p>\n<p>2.\u6c22\u952e\u4f9b\u4f53\u6570\u91cf:1<\/p>\n<p>3.\u6c22\u952e\u53d7\u4f53\u6570\u91cf:1<\/p>\n<p>4.\u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf:0<\/p>\n<p>5.\u4e92\u53d8\u5f02\u6784\u4f53\u6570\u91cf:\u65e0<\/p>\n<p>6.\u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef26<\/p>\n<p>7.\u91cd\u539f\u5b50\u6570\u91cf:9<\/p>\n<p>8.\u8868\u9762\u7535\u8377:0<\/p>\n<p>9.\u590d\u6742\u5ea6:97.1<\/p>\n<p>10.\u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf:0<\/p>\n<p>11.\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>12.\u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>13.\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>14.\u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>15.\u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf:1<\/p>\n<\/p>\n<h2 id=\"xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/h2>\n<p><p>1.\u672c\u54c1\u6709\u6bd2\u3002\u80fd\u5f15\u8d77\u547c\u5438\u7cfb\u7edf\u3001\u795e\u7ecf\u7cfb\u7edf\u53ca\u9020\u8840\u7cfb\u7edf\u7684\u75c5\u53d8\u3002\u5c0f\u9f20\u704c\u80c3\uff2c\uff24\uff15\uff10\uff11\uff10\uff10\uff10\uff4d\uff47\uff0f\uff4b\uff47\uff0c\u5927\u9f20\u704c\u80c3\uff2c\uff24\uff15\uff10\uff17\uff10\uff10\uff4d\uff47\uff0f\uff4b\uff47\u3002\u5927\u9f20\u7684\u55c5\u89c9\u9608\uff10\uff0e\uff10\uff14\uff17\uff4d\uff47\uff0f\uff4d\uff13\uff1b\u773c\u775b\u5149\u611f\u4f4e\uff10\uff0e\uff10\uff12\uff15\uff4d\uff47\uff0f\uff4b\uff47\u3002\u8bbe\u5907\u5e94\u5bc6\u95ed\uff0c\u9632\u6b62\u8dd1\u3001\u5192\u3001\u6ef4\u3001\u6f0f\u3002\u64cd\u4f5c\u65f6\u5e94\u7a7f\u6234\u9632\u62a4\u7528\u5177\uff0c\u907f\u514d\u4e0e\u4eba\u4f53\u76f4\u63a5\u63a5\u89e6\u3002\u64cd\u4f5c\u573a\u6240\u7a7a\u6c14\u4e2d\u9ad8\u5bb9\u8bb8\u6d53\u5ea6\u4e3a\uff10\uff0e\uff10\uff15\uff4d\uff47\uff0f\uff4d\uff13\u3002<\/p>\n<p><strong>2.\u7a33\u5b9a\u6027<sup>[20]<\/sup><\/strong>&nbsp; \u7a33\u5b9a<\/p>\n<p><strong>3.\u7981\u914d\u7269<sup>[21]&nbsp; <\/sup><\/strong>\u9178\u7c7b\u3001\u9170\u57fa\u6c2f\u3001\u9178\u9150\u3001\u5f3a\u6c27\u5316\u5242<\/p>\n<p><strong>4.\u907f\u514d\u63a5\u89e6\u7684\u6761\u4ef6<sup>[22]<\/sup><\/strong>&nbsp; \u53d7\u70ed<\/p>\n<p><strong>5.\u805a\u5408\u5371\u5bb3<sup>[23]<\/sup><\/strong>&nbsp; \u4e0d\u805a\u5408<\/p>\n<p><strong>6.\u5206\u89e3\u4ea7\u7269<sup>[24]<\/sup><\/strong>&nbsp; \u6c2f\u5316\u6c22<\/p>\n<\/p>\n<h2 id=\"zc\">\u8d2e\u5b58\u65b9\u6cd5<\/h2>\n<p><p><strong>\u50a8\u5b58\u6ce8\u610f\u4e8b\u9879<sup>[25]<\/sup><\/strong> 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id=\"hc\">\u5408\u6210\u65b9\u6cd5<\/h2>\n<p><p>1.\u4ee5\u65e0\u6c34\u4e09\u6c2f\u5316\u94c1\u4f5c\u50ac\u5316\u5242\uff0c\u5411105\u2103\u7684\u7194\u878d\u72b6\u6001\u7684\u5bf9\u785d\u57fa\u6c2f\u901a\u5165\u6c2f\u6c14\uff0c\u5f973,4-\u4e8c\u6c2f\u785d\u57fa\u3002\u518d\u5728\u56de\u6d41\u72b6\u6001\u4e0b\u4e0e\u94c1\u7c89\u3001\u7532\u9178\u548c\u6c34\u8fdb\u884c\u8fd8\u539f\u53cd\u5e94\uff0c\u5f97\u52303,4-\u4e8c\u6c2f\u80fa\u30023,4-\u4e8c\u6c2f\u785d\u57fa\u4e5f\u53ef\u4ee5\u7531\u90bb\u4e8c\u6c2f\u785d\u5316\u800c\u5f97\u3002\u5728\u4e0e\u94c1\u7c89\u7684\u8fd8\u539f\u53cd\u5e94\u4e2d\u53ef\u7528\u51b0\u918b\u9178\u4ee3\u66ff\u7532\u9178\u3002\u53e6\u4e00\u79cd\u8fd8\u539f\u65b9\u6cd5\u662f\u50ac\u5316\u52a0\u6c22\u6cd5\u3002<\/p>\n<p>2.\u5176\u5236\u5907\u65b9\u6cd5\u662f\u5728\u53cd\u5e94\u91dc\u4e2d\u52a0\u5165\u5bf9\u6c2f\u785d\u57fa\u3001\u65e0\u6c34\u4e09\u6c2f\u5316\u94c1\u50ac\u5316\u5242\uff0c\u4e8e100\uff5e110\u2103\u901a\u5165\u6c2f\u6c14\uff0c\u5f53\u6d4b\u5b9a\u6c2f\u5316\u53cd\u5e94\u7269\u51dd\u56fa\u70b9\u523030\uff5e31\u2103\u65f6\u5373\u4e3a\u53cd\u5e94\u7ec8\u70b9\u3002\u5c06\u6b64\u7269\u79fb\u81f3\u8fd8\u539f\u91dc\uff0c\u518d\u52a0\u5165\u786b\u4ee3\u94a0(\u4ee5\u6d88\u9664\u53cd\u5e94\u7269\u4e2d\u5269\u4f59\u6c2f\u7684\u5f71\u54cd)\u3001\u7532\u9178\uff0c\u52a0\u70ed\u5230100\u2103(\u56de\u6d41\u72b6\u6001)\u6162\u6162\u52a0\u5165\u94c1\u7c89(\u7ea64\uff5e5h\u52a0\u5b8c)\uff0c\u800c\u540e\u7ee7\u7eed\u4fdd\u6301\u56de\u6d41\u53cd\u5e94\uff0c\u5f53\u89c2\u5bdf\u4e0d\u5230\u785d\u57fa\u5b58\u5728\u65f6\u5373\u4e3a\u53cd\u5e94\u7ec8\u70b9\u3002\u52a0\u51653\uff0c4-\u4e8c\u6c2f\u80fa\u4ea7\u91cf5\uff5e6\u500d\u7684\u6c2f\uff0c\u6405\u62cc0.5\uff5e1.0 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MPa\uff0c\u540c\u65f6\u5347\u6e29\u81f360\uff5e70\u2103\u8fdb\u884c\u53cd\u5e94\uff0c\u76f4\u5230\u4e0d\u5438\u6536\u6c22\u6c14\u4e3a\u6b62\uff0c\u7136\u540e\u51b7\u5374\u7ecf\u540e\u5904\u7406\u53ef\u5f97\u6210\u54c1\u3002<br \/>\u6b64\u5916\uff0c\u4e5f\u53ef\u7528\u90bb\u4e8c\u6c2f\u4e3a\u539f\u6599\uff0c\u7ecf\u785d\u5316\u5f973\uff0c4-\u4e8c\u6c2f\u785d\u57fa\uff0c\u518d\u8fdb\u4e00\u6b65\u8fd8\u539f\u5f97\u6210\u54c1\u3002\u56fd\u5916\u5927\u90e8\u5206\u4f01\u4e1a\u7528\u6b64\u6cd5\u751f\u4ea73\uff0c4-\u4e8c\u6c2f\u80fa\u3002<\/p>\n<\/p>\n<h2 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href=\"https:\/\/www.newtopchem.com\/archives\/45010\">https:\/\/www.newtopchem.com\/archives\/45010<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/catalyst-a400\/\">https:\/\/www.bdmaee.net\/catalyst-a400\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/130-1.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/130-1.jpg<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/cas-753-73-1\/\">https:\/\/www.bdmaee.net\/cas-753-73-1\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/1-methylimidazole\/\">https:\/\/www.bdmaee.net\/1-methylimidazole\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/zinc-octoate-2\/\">https:\/\/www.bdmaee.net\/zinc-octoate-2\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a 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