{"id":1306,"date":"2024-04-23T16:53:23","date_gmt":"2024-04-23T08:53:23","guid":{"rendered":"https:\/\/www.k-15.cn\/index.php\/archives\/1306"},"modified":"2024-04-23T16:53:23","modified_gmt":"2024-04-23T08:53:23","slug":"%e9%9b%8c%e4%b8%89%e9%86%87","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/index.php\/archives\/1306","title":{"rendered":"\u96cc\u4e09\u9187"},"content":{"rendered":"<p>    \t\t\t\t\t\t<img decoding=\"async\" src=\"http:\/\/staticv5.basechem.org\/img\/tupu\/old\/5b97d44af6a440adab122d117fc546a4.gif\" alt=\"\u96cc\u4e09\u9187\u7ed3\u6784\u5f0f\"><\/p>\n<p>\u7ed3\u6784\u5f0f<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">\u7269\u7ade\u7f16\u53f7<\/th>\n<td>013D<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u5f0f<\/th>\n<td>C18H24O3<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u91cf<\/th>\n<td>288.38<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u6807\u7b7e<\/th>\n<td>\n<p>                        16,17-\u4e8c\u7f9f\u753e\u9187,<\/p>\n<p>                        1,3,5(10)-\u4e09\u70ef-3\u0392,16\u0391,17\u0392\u4e09\u9187,<\/p>\n<p>                        \u96cc\u6fc0\u7d20\u4e09\u9187,<\/p>\n<p>                        \u96cc\u753e\u4e09\u9187,<\/p>\n<p>                        (16\u03b1,17\u03b2)-Estra-1,3,5(10)-triene-3,16,17-triol,<\/p>\n<p>                        E3,<\/p>\n<p>                        1,3,5(10)-Estratriene-3,16.\u03b1.,17.\u03b2.-triol,<\/p>\n<p>                        \u96cc\u6fc0\u7d20\u7c7b\u836f<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">\u7f16\u53f7\u7cfb\u7edf<\/a><\/li>\n<li><a href=\"#wx\">\u7269\u6027\u6570\u636e<\/a><\/li>\n<li><a href=\"#dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#st\">\u751f\u6001\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/a><\/li>\n<li><a href=\"#js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                    <a href=\"\" class=\"dropdown-toggle\" data-toggle=\"dropdown\">\u66f4\u591a <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/a><\/li>\n<li><a href=\"#zc\">\u8d2e\u5b58\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#hc\">\u5408\u6210\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#yt\">\u7528\u9014<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">\u7f16\u53f7\u7cfb\u7edf<\/h2>\n<p><b>CAS\u53f7\uff1a<\/b>50-27-1<\/p>\n<p><b>MDL\u53f7\uff1a<\/b>MFCD00003691<\/p>\n<p><b>EINECS\u53f7\uff1a<\/b>200-022-2<\/p>\n<p><b>RTECS\u53f7\uff1a<\/b>KG8225000<\/p>\n<p><b>BRN\u53f7\uff1a<\/b>2508172<\/p>\n<p><b>PubChem\u53f7\uff1a<\/b>24894396<\/p>\n<h2 id=\"wx\">\u7269\u6027\u6570\u636e<\/h2>\n<p><p>1.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u6027\u72b6\uff1a\u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b<\/p>\n<p>2.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u76f8\u5bf9\u5bc6\u5ea6\uff08g\/mL,25\/4\u2103\uff09\uff1a1.27<\/p>\n<p>3.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u76f8\u5bf9\u84b8\u6c7d\u5bc6\u5ea6\uff08g\/mL,\u7a7a\u6c14=1\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>4.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u7194\u70b9\uff08\u00baC\uff09\uff1a280-282&nbsp;\u00b0C(lit.)<\/p>\n<p>5.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u6cb8\u70b9\uff08\u00baC,\u5e38\u538b\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>6.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u6cb8\u70b9\uff08\u00baC, 5.2 kPa\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>7.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u6298\u5c04\u7387\uff1a58 \u00b0 (C=0.4, Dioxane)<\/p>\n<p>8.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u95ea\u70b9\uff08\u00baC\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>9.&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; \u6bd4\u65cb\u5149\u5ea6\uff08\u00ba\uff09\uff1a[\u03b1]<sup>25<\/sup><sub>D<\/sub>+34.4\u00b0(\u5421\u5576)\u3001<sup>25<\/sup><sub>D<\/sub>+58\u00b0\u00b15\u00b0(4%\uff0c\u4e8c\u6c27\u516d\u73af)<\/p>\n<p>10.&nbsp;&nbsp;&nbsp; \u81ea\u71c3\u70b9\u6216\u5f15\u71c3\u6e29\u5ea6\uff08\u00baC\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>11.&nbsp;&nbsp;&nbsp; \u84b8\u6c14\u538b\uff08kPa,25 \u00baC\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>12.&nbsp;&nbsp;&nbsp; \u9971\u548c\u84b8\u6c14\u538b\uff08kPa,60 \u00baC\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>13.&nbsp;&nbsp;&nbsp; \u71c3\u70e7\u70ed\uff08KJ\/mol\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>14.&nbsp;&nbsp;&nbsp; \u4e34\u754c\u6e29\u5ea6\uff08\u00baC\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>15.&nbsp;&nbsp;&nbsp; \u4e34\u754c\u538b\u529b\uff08KPa\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>16.&nbsp;&nbsp;&nbsp; \u6cb9\u6c34\uff08\u8f9b\u9187\/\u6c34\uff09\u5206\u914d\u7cfb\u6570\u7684\u5bf9\u6570\u503c\uff1a\u672a\u786e\u5b9a<\/p>\n<p>17.&nbsp;&nbsp;&nbsp; \u7206\u70b8\u4e0a\u9650\uff08%,V\/V\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>18.&nbsp;&nbsp;&nbsp; \u7206\u70b8\u4e0b\u9650\uff08%,V\/V\uff09\uff1a\u672a\u786e\u5b9a<\/p>\n<p>19.&nbsp;&nbsp;&nbsp; \u6eb6\u89e3\u6027\uff1a\u672c\u6676\u96be\u6eb6\u4e8e\u6c34\uff0c\u5fae\u6eb6\u4e8e(1\uff1a500)\u3001\u3001\u6c2f\u4eff\u3001\u4e8c\u6c27\u516d\u73af\u548c\u690d\u7269\u6cb9\uff0c\u6613\u6eb6\u4e8e\u5421\u5576\u548c\u6c22\u6c27\u5316\u78b1\u6eb6\u6db2<\/p>\n<\/p>\n<h2 id=\"dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"st\">\u751f\u6001\u5b66\u6570\u636e<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/h2>\n<p><p>1\u3001\u6469\u5c14\u6298\u5c04\u7387\uff1a81.09<\/p>\n<p>2\u3001\u6469\u5c14\u4f53\u79ef\uff08cm<sup>3<\/sup>\/mol\uff09\uff1a229.6<\/p>\n<p>3\u3001\u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a622.1<\/p>\n<p>4\u3001\u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a53.8<\/p>\n<p>5\u3001\u6781\u5316\u7387\uff0810-24cm3\uff09\uff1a32.14<\/p>\n<\/p>\n<h2 id=\"js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/h2>\n<p><p>1.\u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09:\u65e0<\/P><\/p>\n<p>2.\u6c22\u952e\u4f9b\u4f53\u6570\u91cf:3<\/p>\n<p>3.\u6c22\u952e\u53d7\u4f53\u6570\u91cf:3<\/p>\n<p>4.\u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf:0<\/p>\n<p>5.\u4e92\u53d8\u5f02\u6784\u4f53\u6570\u91cf:9<\/p>\n<p>6.\u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef60.7<\/p>\n<p>7.\u91cd\u539f\u5b50\u6570\u91cf:21<\/p>\n<p>8.\u8868\u9762\u7535\u8377:0<\/p>\n<p>9.\u590d\u6742\u5ea6:411<\/p>\n<p>10.\u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf:0<\/p>\n<p>11.\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:6<\/p>\n<p>12.\u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>13.\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>14.\u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>15.\u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf:1<\/p>\n<\/p>\n<h2 id=\"xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"zc\">\u8d2e\u5b58\u65b9\u6cd5<\/h2>\n<p><p>\u672c\u54c1\u5bc6\u5c01\u907f\u5149\u5e72\u71e5\u4fdd\u5b58\u3002<\/p>\n<\/p>\n<h2 id=\"hc\">\u5408\u6210\u65b9\u6cd5<\/h2>\n<p><p>1.\u81ea\u4eba\u80ce\u76d8\u7ec4\u7ec7\u3001\u5b55\u5987\u5c3f\u4e2d\u63d0\u53d6\u6216\u5316\u5b66\u5408\u6210\u5236\u5f97\u7684\u96cc\u6fc0\u7d20\u3002&nbsp;<\/p>\n<p>2.\u5de5\u4e1a\u4e0a\u7528\u96cc\u915a\u916e\u4e3a\u539f\u6599\u751f\u4ea7\u3002<\/p>\n<p>3.<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_101122\/201011221109076496.gif\" alt=\"\" \/><\/p>\n<p>4.\u5236\u6cd5\uff1a<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_121225\/201212251403051974.gif\" alt=\"\" \/><\/p>\n<p>1,2,5\uff0810\uff09-\u96cc\u4e09\u9187-16a\uff0c17a-\u73af\u6c27-3,17\u03b2-\u4e8c\u9187\u53cc\u918b\u9178\u916f\uff083\uff09\uff1a\u4e8e\u88c5\u6709\u6405\u62cc\u5668\u3001\u6e29\u5ea6\u8ba1\u3001\u6ef4\u6db2\u6f0f\u6597\u3001\u56de\u6d41\u51b7\u51dd\u5668\u7684\u53cd\u5e94\u74f6\u4e2d\uff0c\u52a0\u51651,3,5\uff0810\uff09\uff0c16-\u96cc\u56db\u70ef-3,17-\u4e8c\u9187\u53cc\u918b\u9178\u916f\uff082\uff0910g\uff0828mmol\uff09\uff0c100mL\uff0c\u65e0\u6c34\u78b3\u9178\u94a010g\uff0c\u65e0\u6c34\u94a013g\uff0c\u6405\u62cc\u4e0b\u6ef4\u52a0\u8fc7\u6c27\uff0820%\uff5e30%\uff0927g\u4e0e\u65e0\u6c3413g\u914d\u6210\u7684\u6eb6\u6db2\uff0c\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\u4e0d\u8d85\u8fc720\u2103\uff0c\u7ea620min\u52a0\u5b8c\u3002\u7ee7\u7eed\u6405\u62cc\u53cd\u5e944h\u3002\u653e\u7f6e\u8fc7\u591c\u3002\u8fc7\u6ee4\uff0c\u6ee4\u997c\u7528\u6d17\u6da4\u3002\u5408\u5e76\u6ee4\u6db2\u548c\u6d17\u6da4\u6db2\uff0c\u4ee5\u78b3\u9178\u6c22\u94a0\u6c34\u6eb6\u6db2\u6d17\u6da4\uff0c\u518d\u6c34\u6d17\u81f3\u4e2d\u6027\u3002\u65e0\u6c34\u94a0\u5e72\u71e5\uff0c\u51cf\u538b\u84b8\u51fa\u3002\u6790\u51fa\u7ed3\u6676\u540e\u9759\u7f6e\u8fc7\u591c\u3002\u62bd\u6ee4\uff0c\u6d17\u6da4\uff0c\u5e72\u71e5\uff0c\u5f971,3,5\uff0810\uff09-\u96cc\u4e09\u9187-16a\uff0c17a-\u73af\u6c27-3,17\u03b2-\u4e8c\u9187\u53cc\u8721\u9178\u916f\uff083\uff099.0g\uff0c\u6536\u738786%\u3002\u6b64\u4e09\u9187\uff081\uff09\uff1a\u4e8e\u88c5\u6709\u6405\u62cc\u5668\u3001\u6e29\u5ea6\u8ba1\u3001\u6ef4\u6db2\u6f0f\u6597\u3001\u56de\u6d41\u51b7\u51dd\u5668\u7684\u53cd\u5e94\u74f6\u4e2d\uff0c\u52a0\u5165\u5316\u5408\u7269\uff083\uff095g\uff0c100mL\uff0c\u6405\u62cc\u4e0b\u6ef4\u52a0\u75311g\uff0c\u6c22\u6c27\u5316\u94be4g\uff0c\u6c3420mL\u914d\u6210\u7684\u6eb6\u6db2\uff0c\u63a7\u5236\u53cd\u5e94\u6e29\u5ea6\u572825\uff5e30\u2103\uff0c\u7ea60.5h\u52a0\u5b8c\uff0c\u800c\u540e\u7ee7\u7eed\u6405\u62cc\u53cd\u5e941h\u3002\u53cd\u5e94\u5b8c\u540e\u7528\u51b0\u918b\u9178\u8c03\u81f3\u5f31\u9178\u6027\u3002\u51cf\u538b\u6d53\u7f29\u81f3\u5e72\u3002\u52a0\u5165\u9002\u91cf\u7684\u6c34\uff0c\u62bd\u6ee4\uff0c\u6ee4\u997c\u7528\u6c34\u6d17\u6da4\u81f3\u4e2d\u6027\uff0c\u4e8e80\u2103\u5e72\u71e5\uff0c\u5f97\u96cc\u4e09\u9187\u7c97\u54c1\u3002\u7c97\u54c1\u4ee520\u500d\u768495%\u7684\u7cbe\u5236\u4e00\u6b21\uff0c\u518d\u7528\u7cbe\u5236\u4e09\u6b21\uff0c\u5f97\u96cc\u4e09\u9187\uff081\uff09\uff0c\u6536\u738750%\u3002<sup>[1]<\/sup><\/p>\n<\/p>\n<h2 id=\"yt\">\u7528\u9014<\/h2>\n<p><p>1.\u7528\u4e8e\u5b50\u5bab\u9888\u708e\uff0c\u5c24\u9002\u7528\u4e8e\u7edd\u7ecf\u671f\u7efc\u5408\u5f81\u3001\u8001\u5e74\u6027\u9634\u9053\u708e\u3002 <\/p>\n<p>2.\u53ef\u7528\u4f5c\u4e2d\u671f\u5f15\u4ea7\u53ca\u4eba\u5de5\u6d41\u4ea7\u7684\u8f85\u52a9\u836f\u7269\u3002 <\/p>\n<p>3.\u7528\u4e8e\u524d\u5217\u817a\u80a5\u5927\u3001\u524d\u5217\u817a\u764c\u7b49\u3002 <\/p>\n<p>4.\u6709\u8fc5\u901f\u5347\u9ad8\u5916\u5468\u767d\u7ec6\u80de\u7684\u4f5c\u7528\uff0c\u4e00\u822c\u5728\u7528\u836f\u540e1\uff5e3\u65e5\u5f00\u59cb\u751f\u6548\uff0c\u4f46\u4f5c\u7528\u7ef4\u6301\u65f6\u95f4\u8f83\u77ed\u3002\u5bf9\u5316\u7597\u6216\u653e\u7597\u5f15\u8d77\u7684\u767d\u7ec6\u80de\u51cf\u5c11\u6709\u6548\u3002 <\/p>\n<p>5.\u80fd\u964d\u4f4e\u8840\u7ba1\u7684\u901a\u900f\u6027\u548c\u8106\u6027\uff0c\u53ef\u7528\u4e8e\u591a\u79cd\u51fa\u8840\u7684\u6cbb\u7597\uff0c\u5bf9\u6708\u7ecf\u8fc7\u591a\u3001\u6241\u6843\u4f53\u6216\u5b50\u5bab\u5207\u9664\u672f\u540e\uff0c\u5747\u6709\u5feb\u901f\u6b62\u8840\u4f5c\u7528\u3002<\/p>\n<\/p>\n<p>    \t\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/jeffcat-nem-catalyst-cas100-74-3-huntsman\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/niax-k-zero-3000-trimer-catalyst-momentive\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/dabco-t-26-catalyst-cas11207-74-9-evonik-germany\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/wp-content\/uploads\/2021\/05\/2-10.jpg<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/687<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/44980<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/44215<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/1041<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/759<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/40230<\/br><\/p>\n","raw":"","protected":false},"excerpt":{"rendered":"<p>\u7ed3\u6784\u5f0f \u7269\u7ade\u7f16\u53f7 013D \u5206\u5b50\u5f0f C18H24O3 \u5206\u5b50\u91cf 288.38 \u6807\u7b7e 16,17-\u4e8c\u7f9f\u753e\u9187, 1,3,5(10)-\u4e09\u70ef-3\u0392,16\u0391,17\u0392\u4e09\u9187, \u96cc\u6fc0\u7d20\u4e09\u9187, \u96cc\u753e\u4e09\u9187, (16\u03b1,17\u03b2)-Estra-1,3,5(10)-triene-3,16,17-triol, E3, 1,3,5(10)-Estra 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