{"id":1289,"date":"2024-04-23T16:01:10","date_gmt":"2024-04-23T08:01:10","guid":{"rendered":"https:\/\/www.k-15.cn\/index.php\/archives\/1289"},"modified":"2024-04-23T16:01:10","modified_gmt":"2024-04-23T08:01:10","slug":"%e5%b7%af%e5%9f%ba%e4%b9%99%e9%85%b8","status":"publish","type":"post","link":"https:\/\/www.k-15.cn\/index.php\/archives\/1289","title":{"rendered":"\u5def\u57fa"},"content":{"rendered":"<p>    \t\t\t\t\t\t<img decoding=\"async\" src=\"http:\/\/staticv5.basechem.org\/img\/tupu\/old\/b0cc20031846454498ab8be5b484070e.gif\" alt=\"\u5def\u57fa\u7ed3\u6784\u5f0f\"><\/p>\n<p>\u7ed3\u6784\u5f0f<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">\u7269\u7ade\u7f16\u53f7<\/th>\n<td>01F5<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u5f0f<\/th>\n<td>C2H4O2S<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u91cf<\/th>\n<td>92.12<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u6807\u7b7e<\/th>\n<td>\n<p>                        \u786b\u9187\u918b\u9178,<\/p>\n<p>                        \u5def\u57fa\u918b\u9178,<\/p>\n<p>                        \u4e59\u786b\u9187\u9178,<\/p>\n<p>                        \u6c22\u786b\u57fa,<\/p>\n<p>                        \u5def\u57fa,<\/p>\n<p>                        \u786b\u4ee3\u9178,<\/p>\n<p>                        \u786b\u6c22\u57fa,<\/p>\n<p>                        \u786b\u9187\u4ee3,<\/p>\n<p>                        ,<\/p>\n<p>                        \u786b\u9187,<\/p>\n<p>                        \u6c22\u786b\u57fa\u918b\u9178,<\/p>\n<p>                        \u5def,<\/p>\n<p>                        Mercaptoacetic acid,<\/p>\n<p>                        2-Mercaptoacetate,<\/p>\n<p>                        2-Mercaptoacetic acid,<\/p>\n<p>                        TGA,<\/p>\n<p>                        \u51b7\u70eb\u53d1\u7528\u836f\u5242,<\/p>\n<p>                        \u805a\u5408\u94fe\u8f6c\u79fb\u5242,<\/p>\n<p>                        \u91d1\u5c5e\u8868\u9762\u5904\u7406\u5242,<\/p>\n<p>                        \u68c0\u5b9a\u94c1\u3001\u94bc\u3001\u94dd\u3001\u9521\u7b49\u7684\u654f\u611f\u8bd5\u5242<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">\u7f16\u53f7\u7cfb\u7edf<\/a><\/li>\n<li><a href=\"#wx\">\u7269\u6027\u6570\u636e<\/a><\/li>\n<li><a href=\"#dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#st\">\u751f\u6001\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/a><\/li>\n<li><a href=\"#js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                    <a href=\"\" class=\"dropdown-toggle\" data-toggle=\"dropdown\">\u66f4\u591a <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/a><\/li>\n<li><a href=\"#zc\">\u8d2e\u5b58\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#hc\">\u5408\u6210\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#yt\">\u7528\u9014<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">\u7f16\u53f7\u7cfb\u7edf<\/h2>\n<p><b>CAS\u53f7\uff1a<\/b>68-11-1<\/p>\n<p><b>MDL\u53f7\uff1a<\/b>MFCD00004876<\/p>\n<p><b>EINECS\u53f7\uff1a<\/b>200-677-4<\/p>\n<p><b>RTECS\u53f7\uff1a<\/b>AI5950000<\/p>\n<p><b>BRN\u53f7\uff1a<\/b>506166<\/p>\n<p><b>PubChem\u53f7\uff1a<\/b>24900165<\/p>\n<h2 id=\"wx\">\u7269\u6027\u6570\u636e<\/h2>\n<p><p>1.\u6027\u72b6\uff1a\u65e0\u8272\u900f\u660e\u6db2\u4f53\uff0c\u6709\u5f3a\u70c8\u4ee4\u4eba\u4e0d\u6109\u5feb\u7684\u6c14\u5473\u3002<sup>[1]<\/sup><\/p>\n<p>2.\u7194\u70b9\uff08\u2103\uff09\uff1a-16.5<sup>[2]<\/sup><\/p>\n<p>3.\u6cb8\u70b9\uff08\u2103\uff09\uff1a120\uff082.67kPa\uff09\uff1b220<sup>[3]<\/sup><\/p>\n<p>4.\u76f8\u5bf9\u5bc6\u5ea6\uff08\u6c34=1\uff09\uff1a1.33<sup>[4]<\/sup><\/p>\n<p>5.\u76f8\u5bf9\u84b8\u6c14\u5bc6\u5ea6\uff08\u7a7a\u6c14=1\uff09\uff1a3.18<sup>[5]<\/sup><\/p>\n<p>6.\u9971\u548c\u84b8\u6c14\u538b\uff08kPa\uff09\uff1a1.47\uff08104~06\u2103\uff09<sup>[6]<\/sup><\/p>\n<p>7.\u4e34\u754c\u538b\u529b\uff08MPa\uff09\uff1a6.1<sup>[7]<\/sup><\/p>\n<p>8.\u8f9b\u9187\/\u6c34\u5206\u914d\u7cfb\u6570\uff1a0.09<sup>[8]<\/sup><\/p>\n<p>9.\u95ea\u70b9\uff08\u2103\uff09\uff1a125<sup>[9]<\/sup><\/p>\n<p>10.\u5f15\u71c3\u6e29\u5ea6\uff08\u2103\uff09\uff1a350<sup>[10]<\/sup><\/p>\n<p>11.\u7206\u70b8\u4e0a\u9650\uff08%\uff09\uff1a\u6682\u65e0\u8d44\u6599<\/p>\n<p>12.\u7206\u70b8\u4e0b\u9650\uff08%\uff09\uff1a5.9<sup>[11]<\/sup><\/p>\n<p>13.\u6eb6\u89e3\u6027\uff1a\u4e0e\u6c34\u6df7\u6eb6\uff0c\u53ef\u6df7\u6eb6\u4e8e\u3001\uff0c\u6eb6\u4e8e\u666e\u901a\u6eb6\u5242\u3002<sup>[12]<\/sup><\/p>\n<\/p>\n<h2 id=\"dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/h2>\n<p><p><strong>1.\u6025\u6027\u6bd2\u6027<strong><sup>[13]<\/sup><\/strong><\/strong>&nbsp; LD50\uff1a\uff1c50mg\/kg\uff08\u5927\u9f20\u7ecf\u53e3\uff09\uff1b250mg\/kg\uff08\u5c0f\u9f20\u7ecf\u53e3\uff09<\/p>\n<p><strong>2.\u523a\u6fc0\u6027<\/strong>&nbsp; \u6682\u65e0\u8d44\u6599<\/p>\n<\/p>\n<h2 id=\"st\">\u751f\u6001\u5b66\u6570\u636e<\/h2>\n<p><p><strong>1.\u751f\u6001\u6bd2\u6027<\/strong>&nbsp; \u6682\u65e0\u8d44\u6599<\/p>\n<p><strong>2.\u751f\u7269\u964d\u89e3\u6027<strong><sup>[14]<\/sup><\/strong><\/strong>&nbsp; MITI-I\u6d4b\u8bd5\uff0c\u521d\u59cb\u6d53\u5ea6100ppm\uff0c\u6c61\u6ce5\u6d53\u5ea630ppm\uff0c4\u5468\u540e\u964d\u89e3100%\u3002<\/p>\n<p><strong>3.\u975e\u751f\u7269\u964d\u89e3\u6027<strong><sup>[15]<\/sup><\/strong>&nbsp; <\/strong>\u7a7a\u6c14\u4e2d\uff0c\u5f53\u7f9f\u57fa\u81ea\u7531\u57fa\u6d53\u5ea6\u4e3a5.00\u00d710<sup>5<\/sup>\u4e2a\/cm<sup>3<\/sup>\u65f6\uff0c\u964d\u89e3\u534a\u8870\u671f\u4e3a10h\uff08\u7406\u8bba\uff09\u3002<\/p>\n<\/p>\n<h2 id=\"fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/h2>\n<p><p>1\u3001\u6469\u5c14\u6298\u5c04\u7387\uff1a20.77<\/p>\n<p>2\u3001\u6469\u5c14\u4f53\u79ef\uff08cm<sup>3<\/sup>\/mol\uff09\uff1a70.2<\/p>\n<p>3\u3001\u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a185.3<\/p>\n<p>4\u3001\u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a48.5<\/p>\n<p>5\u3001\u4ecb\u7535\u5e38\u6570\uff1a\u65e0\u53ef\u7528\u7684<\/p>\n<p>6\u3001\u6781\u5316\u7387\uff0810<sup>-24<\/sup>cm<sup>3<\/sup>\uff09\uff1a8.23<\/p>\n<p>7\u3001\u5355\u4e00\u540c\u4f4d\u7d20\u8d28\u91cf\uff1a91.993199 Da<\/p>\n<p>8\u3001\u6807\u79f0\u8d28\u91cf\uff1a92 Da<\/p>\n<p>9\u3001\u5e73\u5747\u8d28\u91cf\uff1a92.117 Da<\/p>\n<\/p>\n<h2 id=\"js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/h2>\n<p><p>1\u3001\u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09\uff1a0.1<\/p>\n<p>2\u3001\u6c22\u952e\u4f9b\u4f53\u6570\u91cf\uff1a2<\/p>\n<p>3\u3001\u6c22\u952e\u53d7\u4f53\u6570\u91cf\uff1a3<\/p>\n<p>4\u3001\u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf\uff1a1<\/p>\n<p>5\u3001\u4e92\u53d8\u5f02\u6784\u4f53\u6570\u91cf\uff1a\u65e0<\/p>\n<p>6\u3001\u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef\uff08TPSA\uff09\uff1a38.3<\/p>\n<p>7\u3001\u91cd\u539f\u5b50\u6570\u91cf\uff1a5<\/p>\n<p>8\u3001\u8868\u9762\u7535\u8377\uff1a0<\/p>\n<p>9\u3001\u590d\u6742\u5ea6\uff1a42.9<\/p>\n<p>10\u3001\u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf\uff1a0<\/p>\n<p>11\u3001\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>12\u3001\u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>13\u3001\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>14\u3001\u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>15\u3001\u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf\uff1a1<\/p>\n<\/p>\n<h2 id=\"xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/h2>\n<p><p>1. \u5728\u7a7a\u6c14\u4e2d\u8fc5\u901f\u6c27\u5316\uff0c\u5c11\u91cf\u94dc\u3001\u94c1\u3001\u9530\u79bb\u5b50\u7684\u5b58\u5728\u80fd\u52a0\u901f\u6c27\u5316\u8fc7\u7a0b\u3002\u6d53\u5ea6\u5c0f\u4e8e70%\uff08\u91cd\u91cf\uff09\u7684\u5def\u57fa\u6c34\u6eb6\u6db2,\u5728\u5ba4\u6e29\u4e0b\u8d2e\u5b58\u662f\u7a33\u5b9a\u7684\u3002\u5728\u9ad8\u6d53\u5ea6\u65f6\uff0c\u5219\u4f1a\u751f\u6210\u4e00\u5b9a\u91cf\u7684\u5404\u79cd\u81ea\u916f\u5316\u7269\u3002\u9047\u660e\u706b\u3001\u9ad8\u70ed\u80fd\u71c3\u70e7\u5e76\u653e\u51fa\u6709\u5267\u6bd2\u7684\u786b\u5316\u6c22\u6c14\u4f53\u3002<\/p>\n<p><strong>2.\u7a33\u5b9a\u6027<sup>[16]<\/sup><\/strong>&nbsp; \u7a33\u5b9a<\/p>\n<p><strong>3.\u7981\u914d\u7269<sup>[17]<\/sup><\/strong>&nbsp; \u5f3a\u6c27\u5316\u5242<\/p>\n<p><strong>4.\u907f\u514d\u63a5\u89e6\u7684\u6761\u4ef6<sup>[18]<\/sup><\/strong>&nbsp; \u53d7\u70ed<\/p>\n<p><strong>5.\u805a\u5408\u5371\u5bb3<sup>[19]<\/sup><\/strong>&nbsp; \u4e0d\u805a\u5408<\/p>\n<p><strong>6.\u5206\u89e3\u4ea7\u7269<sup>[20]<\/sup><\/strong>&nbsp; \u786b\u5316\u7269<\/p>\n<\/p>\n<h2 id=\"zc\">\u8d2e\u5b58\u65b9\u6cd5<\/h2>\n<p><p><strong>\u50a8\u5b58\u6ce8\u610f\u4e8b\u9879<strong><sup>[21]<\/sup><\/strong><\/strong>&nbsp; \u50a8\u5b58\u4e8e\u9634\u51c9\u3001\u901a\u98ce\u7684\u5e93\u623f\u3002\u8fdc\u79bb\u706b\u79cd\u3001\u70ed\u6e90\u3002\u4fdd\u6301\u5bb9\u5668\u5bc6\u5c01\u3002\u5e94\u4e0e\u6c27\u5316\u5242\u5206\u5f00\u5b58\u653e\uff0c\u5207\u5fcc\u6df7\u50a8\u3002\u914d\u5907\u76f8\u5e94\u54c1\u79cd\u548c\u6570\u91cf\u7684\u6d88\u9632\u5668\u6750\u3002\u50a8\u533a\u5e94\u5907\u6709\u6cc4\u6f0f\u5e94\u6025\u5904\u7406\u8bbe\u5907\u548c\u5408\u9002\u7684\u6536\u5bb9\u6750\u6599\u3002<\/p>\n<\/p>\n<h2 id=\"hc\">\u5408\u6210\u65b9\u6cd5<\/h2>\n<p><p>1.\u7531\u65e0\u673a\u6216\u6709\u673a\u542b\u786b\u5316\u5408\u7269\u4e0e\u4e00\u6c2f\u7684\u94a0\u3001\u94be\u76d0\u53cd\u5e94\u5219\u5f97\u3002\u5982\uff1a\u4e00\u6c2f\u4e0e\u786b\u5316\u94a0\u3001\u786b\u78fa\u53cd\u5e94\u751f\u6210\u4e8c\u786b\u4e8c\uff0c\u7136\u540e\u7528\u950c\u548c\u9178\u8fd8\u539f\uff1b\u6216\u786b\u4ee3\u6c28\u57fa\u7532\u9178\u916f\u4e0e\u4e00\u6c2f\u53cd\u5e94\uff0c\u5176\u4ea7\u7269\u7ecf\u6c34\u89e3\u5236\u5f97\uff1b\u4e00\u6c2f\u4e0e\u786b\u8132\u53cd\u5e94\uff0c\u751f\u6210\u5f02\u786b\u8132\u4ee3\uff0c\u7136\u540e\u7528\u6c22\u6c27\u5316\u94a1\u8f6c\u5316\u6c89\u6dc0\uff0c\u518d\u7528\u9178\u5316\u5236\u6210\u5def\u57fa\u6c34\u6eb6\u6db2\uff0c\u7ecf\u84b8\u53d1\u53ef\u5236\u5f9760%-70%\u6eb6\u6db2\uff0c\u6536\u738770%\u4ee5\u4e0a\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_100915\/201009150918595407.gif\" alt=\"\" \/><\/p>\n<p>2.\u5728\u6e29\u5ea6\u4e0d\u8d85\u8fc725\u2103\u4e0b\uff0c\u5c06\u78b3\u9178\u94a0\u6eb6\u6db2\u52a0\u5230\u6c2f\u4e2d\u81f3ph\u503c7\uff5e8\uff0c\u7136\u540e\u52a0\u5165\u786b\u8132\u53cd\u5e94\uff0c\u751f\u6210\u8132\uff0c\u6240\u5f97\u786b\u8132\u5728\u4fdd\u6e2978\uff5e80\u2103\u4e0b\u4e0e\u6c22\u6c27\u5316\u94a0\u53cd\u5e942h\uff0c\u53cd\u5e94\u7ed3\u675f\u540e\u51b7\u5374\u81f340\u2103\uff0c\u52a0\u5165\u6d53\u76d0\u9178\u81f3ph\u503c\u4e3a3\uff0c\u518d\u7528\u8403\u53d6\uff0c\u8403\u53d6\u6240\u5f97\u5c42\u52a0\u5165\u6d3b\u6027\u70ad\u5145\u5206\u6405\u62cc\u540e\u8fc7\u6ee4\uff0c\u6ee4\u6db2\u52a0\u950c\u7c89\u540e\u51cf\u538b\u7cbe\u998f\uff0c\u5373\u5f97\u7eaf\u54c1\u786b\u4ee3\u9178\u3002<br \/>\u8fc7\u7a0b\u53cd\u5e94\u5f0f\u4e3a\uff1a<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_101008\/201010081508149542.gif\" alt=\"\" \/><\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_101008\/201010081508282357.gif\" alt=\"\" \/><\/p>\n<p>3.\u6405\u62cc\u4e0b\u5c0616%\u7684\u6c2f\u6c34\u6eb6\u6db2\u4e0e15%\u7684\u786b\u6c22\u5316\u94be\u6c34\u6eb6\u6db2\u6df7\u5408\uff0cClCH2COOH\u2236KHS\uff1d1\u2236 2\uff08 \u6469\u5c14\u6bd4\uff09 \u3002\u52a0\u70ed\uff0c\u52a0\u5165\u4e0e\u6c2f\u76f8\u540c\u7269\u8d28\u91cf\u7684\u6c2f\u5316\u94a1\u9971\u548c\u6eb6\u6db2\uff0c\u7136\u540e\u52a0\u516525%\u7684\u6d53\u6c28\u6c34\uff0c\u6405\u62cc\u5747\u5300\u540e\uff0c\u9759\u7f6e\uff0c\u8fc7\u6ee4\uff0c\u6ee4\u6db2\u4e2d\u52a0\u5165\u7b49\u4f53\u79ef\u7684\u6d53\u76d0\u9178\uff0c\u518d\u7528\u8403\u53d6\uff0c\u84b8\u998f\u9664\u53bb\uff0c\u540e\uff0c\u57282000Pa\u84b8\u998f\uff0c\u6536\u96c6104\uff5e106\u2103\u998f\u5206\uff0c\u5373\u5f97\u6210\u54c1\u786b\u4ee3\u9178\u3002<br \/>\u53cd\u5e94\u5f0f\u4e3a\uff1a<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_101008\/201010081508501442.gif\" alt=\"\" \/><\/p>\n<p>4.\u786b\u6c22\u5316\u94a0\u548c\u6c2f\u5728\u786b\u5316\u6c22\u548c\u6c2e\u6c14\u7684\u4f5c\u7528\u4e0b\u5236\u5f97\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_101105\/201011051026262428.gif\" alt=\"\" \/><\/p>\n<p>5.\u6c2f\u3001\u786b\u4ee3\u94a0\u4e0e\u6c22\u6c27\u5316\u94a0\u5408\u6210\uff0c\u7136\u540e\u7ecf\u9178\u89e3\u3001\u8403\u53d6\u3001\u84b8\u998f\u5f97\u5230\u6210\u54c1\u3002<\/p>\n<\/p>\n<h2 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\t\u6269\u5c55\u9605\u8bfbhttps:\/\/www.newtopchem.com\/archives\/44386<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.cyclohexylamine.net\/polyurethane-delayed-catalyst-sa-1-tertiary-amine-delayed-catalyst\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/wp-content\/uploads\/2020\/06\/27.jpg<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/2-dimorpholinodiethylether\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.cyclohexylamine.net\/category\/product\/page\/28\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/dmp-30\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/toyocat-rx3-organic-amine-catalyst-tosoh\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/n-methyl-pyrrolidone-nmp-cas872-50-4\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.cyclohexylamine.net\/strong-gel-amine-catalyst-bx405-low-odor-amine-catalyst-bx405\/<\/br>\u6269\u5c55\u9605\u8bfbhttps:\/\/www.bdmaee.net\/anhydrous-tin-tetrachloride-2\/<\/br><\/p>\n","raw":"","protected":false},"excerpt":{"rendered":"<p>\u7ed3\u6784\u5f0f 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